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Cycloisomerization of Enynes Catalyzed by Iron(0)-Ate Complexes


"Cycloisomerization of Enynes Catalyzed by Iron(0)-Ate Complexes"
Alois Fürstner, Rubén Martin, and Keisuke Majima

J. Am. Chem. Soc. 2005, 127, 12236-12237. DOI Link

Handout: Download PDF

Presented by Thomas Jensen.

01 Feb 2008

Enantioselective Allylation of Imines


"Highly Enantioselective Imine Cinnamylation with a Remarkable Diastereochemical Switch"
John D. Huber and James L. Leighton

J. Am. Chem. Soc. 2007, 129, 14552-14553. DOI Link

"Enantioselective Imidazole-Directed Allylation of Aldimines and Ketimines"
Nicholas R. Perl and James L. Leighton

Org. Lett. 2007, 9, 3699-3701. DOI Link

Handout: Download PDF

Presented by Amanda Jones.

18 Jan 2008

Enantioselective α-Arylation of Ketones


"Enantioselective α-Arylation of Ketones with Aryl Triflates Catalyzed by Difluorphos Complexes of Palladium and Nickel"
Xuebin Liao, Zhiqiang Weng, and John F. Hartwig

J. Am. Chem. Soc. 2008, 130, 195-200. DOI Link

Presented by Hosea Nelson.

21 Dec 2007

Rates and mechanisms of oxidative addition to zerovalent palladium complexes generated in situ from mixtures of Pd0(dba)2 and triphenylphosphine


"Rates and mechanisms of oxidative addition to zerovalent palladium complexes generated in situ from mixtures of Pd0(dba)2 and triphenylphosphine"
Christian Amatore, Anny Jutand, Fouad Khalil, Mohamed A. M'Barki, Loic Mottier

Organometallics 1993, 12, 3168-3178. Document

Presented by Chris Gilmore.

09 Nov 2007

Enantioselective Iridium-Catalyzed Imine Vinylation: Optically Enriched Allylic Amines via Alkyne-Imine Reductive Coupling Mediated by Hydrogen


"Enantioselective Iridium-Catalyzed Imine Vinylation: Optically Enriched Allylic Amines via Alkyne-Imine Reductive Coupling Mediated by Hydrogen"
Ming-Yu Ngai, Andriy Barchuk, and Michael J. Krische

J. Am. Chem. Soc. 2007, 129, 12644-12645. DOI Link

Presented by Sandy Ma.

19 Oct 2007

Catalytic and Highly Regioselective Cross-Coupling of Aromatic C-H Substrates


"Catalytic and Highly Regioselective Cross-Coupling of Aromatic C-H Substrates"
Kami L. Hull and Melanie S. Sanford

J. Am. Chem. Soc. 2007, 129, 11904-11905. DOI Link

Handout: Download PDF

Presented by Chris Gilmore.

21 Sep 2007

Rhodium-Catalyzed 5 + 2 Reactions


"On the Mechanism of [Rh(CO)2Cl]2-Catalyzed Intermolecular (5 + 2) Reactions between Vinylcyclopropanes and Alkynes"
Zhi-Xiang Yu, Paul A. Wender, and K. N. Houk

J. Am. Chem. Soc. 2004, 126, 9154 -9155. DOI Link

Presented by Pam Tadross.

21 Jun 2007

Ruthenium-Catalyzed Regiospecific Borylation of Methyl C-H Bonds


"Ruthenium-Catalyzed Regiospecific Borylation of Methyl C-H Bonds"
Jaclyn M. Murphy, Joshua D. Lawrence, Kazumori Kawamura, Christopher Incarvito, and John F. Hartwig

J. Am. Chem. Soc. 2006, 128, 13684 -13685. DOI Link

Presented by Chris Daeffler.

02 Jan 2007

Cyanoesterification of 1,2-Dienes: Synthesis and Transformations of Highly Functionalized Cyanomethylacrylate Esters


"Cyanoesterification of 1,2-Dienes: Synthesis and Transformations of Highly Functionalized Cyanomethylacrylate Esters "
Tamehiro Hiyama, Yoshiaki Nakao, et. al.

J. Am. Chem. Soc.; 2006; 128 pp 7420 - 7421. DOI Link

Presented by Sandy Ma.

21 Jul 2006

Hydroheteroarylation of Alkynes under Mild Nickel Catalysis


"Hydroheteroarylation of Alkynes under Mild Nickel Catalysis"
Yoshiaki Nakao, Kyalo Stephen Kanyiva, Shinichi Oda, and Tamejiro Hiyama

J. Am. Chem. Soc.; 2006; 128(25) pp 8146 - 8147. DOI Link

Presented by Dave Ebner.

23 Jun 2006

Palladium-Catalyzed Ring Enlargement of Aryl-Substituted Methylenecyclopropanes to Cyclobutenes


"Palladium-Catalyzed Ring Enlargement of Aryl-Substituted Methylenecyclopropanes to Cyclobutenes"
Min Shi, Le-Ping Liu, and Jie Tang

J. Am. Chem. Soc.; 2006; 128(23) pp 7430 - 7431. DOI Link

Presented by Ryan McFadden.

26 May 2006

Stereoselective [3,3]-Sigmatropic Rearrangement Promoted by the Metal [1,3]-Shift of Binuclear Fischer Carbene Complexes


"Stereoselective [3,3]-Sigmatropic Rearrangement Promoted by the Metal [1,3]-Shift of Binuclear Fischer Carbene Complexes"
Ken Kamikawa, Atsushi Tachibana, Yasunori Shimizu, Kazuya Uchida, Masaru Furusho, and Motokazu Uemura

Org. Lett.; 2004; 6(23) pp 4307 - 4310. DOI Link

Presented by JT Mohr.

28 Apr 2006

Pd(II)-Catalyzed Enantioselective Oxidative Tandem Cyclization Reactions


"Pd(II)-Catalyzed Enantioselective Oxidative Tandem Cyclization Reactions. Synthesis of Indolines through C-N and C-C Bond Formation"
Kai-Tai Yip, Min Yang, Ka-Lun Law, Nian-Yong Zhu, and Dan Yang

J. Am. Chem. Soc.; 2006; 128(10) pp 3130 - 3131. DOI Link

Presented by Brinton Seashore-Ludlow.

31 Mar 2006

Copper-Catalyzed γ-Selective and Stereospecific Substitution Reaction of Allylic Carbonates with Diboron


"Copper-Catalyzed γ-Selective and Stereospecific Substitution Reaction of Allylic Carbonates with Diboron: Efficient Route to Chiral Allylboron Compounds"
Hajime Ito, Chika Kawakami, and Masaya Sawamura

J. Am. Chem. Soc.; 2005; 127(46) pp 16034 - 16035. DOI Link

Presented by Chris Douglas.

03 Feb 2006

Rhodium-Catalyzed Isomerization of α-Arylpropargyl Alcohols to Indanones


"Rhodium-Catalyzed Isomerization of α-Arylpropargyl Alcohols to Indanones: Involvement of an Unexpected Reaction Cascade"
Ryo Shintani, Kazuhiro Okamoto, and Tamio Hayashi

J. Am. Chem. Soc.; 2005; 127(9) pp 2872 - 2873. DOI Link

Presented by Mike Krout.

13 Jan 2006

Gold-Catalyzed Carbene Transfer Reactions


"A Gold Catalyst for Carbene-Transfer Reactions from Ethyl Diazoacetate"
Manuel R. Fructos, Tomás R. Belderrain, Pierre de Frémont, Natalie M. Scott, Steven P. Nolan, M. Mar Díaz-Requejo, and Pedro J. Pérez

Angew. Chem., Int. Ed.; 2005; 44(33) pp 5284 - 5288. DOI Link

Presented by Mike Krout.

23 Sep 2005

Ruthenium-catalyzed Selective C-H Bond Functionalization


"Selective and Catalytic Arylation of N-Phenylpyrrolidine: sp3 C-H Bond Functionalization in the Absence of a Directing Group"
Bengü Sezen and Dalibor Sames

J. Am. Chem. Soc.; 2005; 127(15) pp 5284 - 5285. DOI Link

Handout: Download PDF

Presented by Tom Driver.

19 Aug 2005

Chiral Propargylic Compounds from Ruthenium Allenylidenes


"Novel Method for the Preparation of Enantiomerically Pure Propargylic Substituted Compounds"
Yoshiaki Nishibayashi, Hiroaki Imajima, Gen Onodera, and Sakae Uemura

Organometallics; 2005; 24(17) pp 4106 - 4109. DOI Link

Presented by Raissa Trend.

29 Jul 2005

Pd-Catalyzed Five Component Tandem Reaction


"Intermolecular Tandem Pd-Catalyzed Cross-Coupling/[4+4] and [4+2] Cycloadditions: A One-Pot, Five-Component Assembly of Bicyclo[6.4.0]dodecanes"
Phil Ho Lee, Kooyeon Lee

Angew. Chem., Int. Ed.; 2005; 44(21) pp 3253 - 3256. DOI Link

Presented by JT Mohr.

08 Jul 2005

Fe-Catalyzed Couplings


"Iron-Catalyzed Aryl-Aryl Cross-Couplings with Magnesium-Derived Copper Reagents"
Ioannis Sapountzis, Wenwei Lin, Christiane C. Kofink, Christina Despotopoulou, Paul Knochel

Angew. Chem., Int. Ed.; 2005; 44(11) pp 1654 - 1658. DOI Link

Presented by Dave Ebner.

22 Apr 2005

Platinum-Catalyzed Dehydrogenative Coupling


"Intermolecular and Intramolecular, Platinum-Catalyzed, Acceptorless Dehydrogenative Coupling of Hydrosilanes with Aryl and Aliphatic Methyl C-H Bonds"
Naofumi Tsukada and John F. Hartwig

J. Am. Chem. Soc.; 2005; 127(14) pp 5022 - 5023. DOI Link

Presented by Ryan McFadden.

25 Mar 2005

Tandem Rhodium-Catalyzed Cyclopropanation/ Cope Rearrangement


"Metal Carbene-Promoted Sequential Transformations for the Enantioselective Synthesis of Highly Functionalized Cycloheptadienes"
Liang Deng, Anthony J. Giessert, Oksana O. Gerlitz, Xing Dai, Steven T. Diver, and Huw M. L. Davies

J. Am. Chem. Soc.; 2005; 127(5) pp 1342 - 1343. DOI Link

Presented by Dan Caspi.

11 Feb 2005

Ruthenium-Catalyzed Cycloisomerization of Diyne-ols


"Regioselectivity Control in a Ruthenium-Catalyzed Cycloisomerization of Diyne-ols"
Barry M. Trost, Michael T. Rudd, Moisés Gulías Costa, Philip I. Lee, and Andrew E. Pomerantz

Org. Lett.; 2004; 6(23) pp 4235 - 4238. DOI Link

Presented by Tim Funk.

14 Jan 2005

The Chemistry of Palladium Hydrides


"Elucidating Reactivity Differences in Palladium-Catalyzed Coupling Processes: The Chemistry of Palladium Hydrides"
Ivory D. Hills and Gregory C. Fu

J. Am. Chem. Soc.; 2004; 126(41) pp 13178 - 13179. DOI Link

Presented by Mike Krout.

01 Oct 2004

Platinum-Catalyzed Intramolecular Hydroalkoxylation of - and -Hydroxy Olefins to Form Cyclic Ethers


"Platinum-Catalyzed Intramolecular Hydroalkoxylation of - and -Hydroxy Olefins to Form Cyclic Ethers"
Hua Qian, Xiaoqing Han, and Ross A. Widenhoefer

J. Am. Chem. Soc.; 2004; 126(31) pp 9536 - 9537. DOI Link

Presented by Donde Anderson.

10 Sep 2004

Nickel-Catalyzed Intermolecular [3 + 2 + 2] Cocyclization of Ethyl Cyclopropylideneacetate and Alkynes


"Nickel-Catalyzed Intermolecular [3 + 2 + 2] Cocyclization of Ethyl Cyclopropylideneacetate and Alkynes"
Shinichi Saito, Manami Masuda, and Shinsuke Komagawa

J. Am. Chem. Soc. 2004; 126(34) pp 10540 -10541. DOI Link

Presented by Dan Caspi.

20 Aug 2004

Palladium-Catalyzed Electrophilic Substitution via Monoallylpalladium Intermediates


"Palladium-Catalyzed Electrophilic Substitution via Monoallylpalladium Intermediates"
Niclas Solin, Johan Kjellgren, and Kalman J. Szabo

Angew. Chem. Int. Ed. 2003; 42(31) pp 3656-3658. DOI Link

Presented by Dave Ebner.

09 Jul 2004

A New Chiral Rh(II) Catalyst for Enantioselective [2 + 1]-Cycloaddition


"A New Chiral Rh(II) Catalyst for Enantioselective [2 + 1]-Cycloaddition. Mechanistic Implications and Applications"
Yan Lou, Manabu Horikawa, Robin A. Kloster, Natalie A. Hawryluk, and E. J. Corey

J. Am. Chem. Soc. 2004; 126(29) pp 8916 -8918. DOI Link

Presented by Jeff Bagdanoff.

02 Jul 2004

The Generation and Reaction of Tungsten-Containing Azomethine Ylides


"A Facile Method for the Synthesis of Polycyclic Indole Derivatives: The Generation and Reaction of Tungsten-Containing Azomethine Ylides"
Hiroyuki Kusama, Jun Takaya, and Nobuharu Iwasawa

J. Am. Chem. Soc. 2002; 124 (39) pp 11592 -11593. DOI Link

Presented by JT Mohr.

28 May 2004

Amine-Salt-Controlled, Catalytic Asymmetric Conjugate Addition of Various Amines and Asymmetric Protonation


"Amine-Salt-Controlled, Catalytic Asymmetric Conjugate Addition of Various Amines and Asymmetric Protonation"
Yoshitaka Hamashima, Hidenori Somei, Yuta Shimura, Toshihiro Tamura, and Mikiko Sodeoka

Org. Lett.; 2004 6(11) pp 1861 -1864. DOI Link

Presented by Raissa Trend.

14 May 2004

Phosphine Catalyzed α-Arylation of Enones and Enals Using Hypervalent Bismuth Reagents: Regiospecific Enolate Arylation via Nucleophilic Catalysis


"Phosphine Catalyzed α-Arylation of Enones and Enals Using Hypervalent Bismuth Reagents: Regiospecific Enolate Arylation via Nucleophilic Catalysis"
Phillip K. Koech and Michael J. Krische

J. Am. Chem. Soc. 2004; 126(17) pp 5350 -5351. DOI Link

Presented by Ryan McFadden.

16 Apr 2004

Parallel Kinetic Resolution of 4-Alkynals Catalyzed by Rh(I)/Tol-BINAP


"Parallel Kinetic Resolution of 4-Alkynals Catalyzed by Rh(I)/Tol-BINAP: Synthesis of Enantioenriched Cyclobutanones and Cyclopentenones"
Ken Tanaka and Gregory C. Fu

J. Am. Chem. Soc. 2003; 125(27) pp 8078 -8079. DOI Link

Presented by JT Mohr.

06 Feb 2004

Intermediacy of an N-Heterocyclic Carbene Complex in the Catalytic C-H Activation of a Substituted Benzimidazole


"Intermediacy of an N-Heterocyclic Carbene Complex in the Catalytic C-H Activation of a Substituted Benzimidazole"
Kian L. Tan, Robert G. Bergman, and Jonathan A. Ellman

J. Am. Chem. Soc. 2002; 124(13) pp 3202 -3203. DOI Link

Presented by Ryan McFadden.

23 Jan 2004

Annulation of Alkenyl-Substituted Heterocycles via Rhodium-Catalyzed Intramolecular C-H Activated Coupling Reactions


"Annulation of Alkenyl-Substituted Heterocycles via Rhodium-Catalyzed Intramolecular C-H Activated Coupling Reactions"
K. L. Tan, R. G. Bergman, and J. A. Ellman

J. Am. Chem. Soc. 2001; 123(11) pp 2685 -2686. DOI Link

Presented by Eric Ferreira.

09 Jan 2004

Toward an Improved Understanding of the Unusual Reactivity of Pd(0)/Trialkylphosphane Catalysts in Cross-Couplings of Alkyl Electrophiles: Quantifying the Factors That Determine the Rate of Oxidative Addition


"Toward an Improved Understanding of the Unusual Reactivity of Pd(0)/Trialkylphosphane Catalysts in Cross-Couplings of Alkyl Electrophiles: Quantifying the Factors That Determine the Rate of Oxidative Addition"
Ivory D. Hills, Matthew R. Netherton, Dr., Gregory C. Fu, Prof. Dr.

Angew. Chem. Int. Ed. 2003; 42(46); 5749-5752. DOI Link

Presented by [unknown]

07 Dec 2003

The First Applications of Carbene Ligands in Cross-Couplings of Alkyl Electrophiles: Sonogashira Reactions of Unactivated Alkyl Bromides and Iodides


"The First Applications of Carbene Ligands in Cross-Couplings of Alkyl Electrophiles: Sonogashira Reactions of Unactivated Alkyl Bromides and Iodides"
Matthias Eckhardt and Gregory C. Fu

J. Am. Chem. Soc.; 2003; 125(45) pp 13642 - 13643. DOI Link

Presented by [unknown].

21 Nov 2003

Oxidative Addition of 2-Haloalkene to Zirconocene
"Oxidative Addition of 2-Haloalkene to Zirconocene "
Tamotsu Takahashi, Martin Kotora, Reinald Fischer, Yasushi Nishihara, Kiyohiko Nakajima;

J. Am. Chem. Soc.; 1995; 117(44); 11039-11040. DOI Link

Presented by Neil Garg.

07 Nov 2003

Clean Inversion of Configuration in the Pd-Catalyzed Cross-Coupling of 2-Bromo-1,3-dienes


"Clean Inversion of Configuration in the Pd-Catalyzed Cross-Coupling of 2-Bromo-1,3-dienes"
Xingzhong Zeng, Qian Hu, Mingxing Qian, and Ei-ichi Negishi

J. Am. Chem. Soc.; 2003; 125(45) pp 13636 - 13637. DOI Link

Presented by Ryan McFadden.

24 Oct 2003

Catalytic Asymmetric Rearrangement of Allylic Trichloroacetimidates


"Catalytic Asymmetric Rearrangement of Allylic Trichloroacetimidates. A Practical Method for Preparing Allylic Amines and Congeners of High Enantiomeric Purity"
Carolyn E. Anderson and Larry E. Overman

J. Am. Chem. Soc. 2003;125(41) pp 12412 -12413. DOI Link

Presented by Dan Caspi.

10 Oct 2003

Palladium(0)-Catalyzed Cope Rearrangement of Acyclic 1,5-Dienes


"Palladium(0)-Catalyzed Cope Rearrangement of Acyclic 1,5-Dienes. Bis(-allyl)palladium(II) Intermediate"
Hiroyuki Nakamura, Hideki Iwama, Masateru Ito, and Yoshinori Yamamoto

J. Am. Chem. Soc. 1999; 121(46) pp 10850 -10851. DOI Link

Presented by Dave Ebner.

26 Sep 2003

A New Type of Catalytic Tandem 1,4-Addition-Aldol Reaction Which Proceeds through an (Oxa--allyl)rhodium Intermediate


"A New Type of Catalytic Tandem 1,4-Addition-Aldol Reaction Which Proceeds through an (Oxa--allyl)rhodium Intermediate"
Kazuhiro Yoshida, Masamichi Ogasawara, and Tamio Hayashi

J. Am. Chem. Soc.; 2002; 124(37) pp 10984 - 10985. DOI Link

Presented by [unknown].

12 Sep 2003

Catalytic Enantioselective Conjugate Reduction of Lactones and Lactams


"Catalytic Enantioselective Conjugate Reduction of Lactones and Lactams"
Gregory Hughes, Masanari Kimura, and Stephen L. Buchwald

J. Am. Chem. Soc.; 2003; 125(37) pp 11253 - 11258. DOI Link

Presented by [unknown].

29 Aug 2003

Catalytic Enone Cycloallylation via Concomitant Activation of Latent Nucleophilic and Electrophilic Partners: Merging Organic and Transition Metal Catalysis


"Catalytic Enone Cycloallylation via Concomitant Activation of Latent Nucleophilic and Electrophilic Partners: Merging Organic and Transition Metal Catalysis"
Bradley G. Jellerichs, Jong-Rock Kong, and Michael J. Krische

J. Am. Chem. Soc.; 2003; 125(26) pp 7758 - 7759. DOI Link

Presented by [unknown].

15 Aug 2003

Asymmetric Allylic Alkylations with Alcohol Pronucleophiles
"A Two-Component Catalyst System for Asymmetric Allylic Alkylations with Alcohol Pronucleophiles"
Barry M. Trost, Ernest J. McEachern, and F. Dean Toste

J. Am. Chem. Soc. 1998; 120(48) pp 12702 -12703. DOI Link

Presented by Uttam Tambar.

01 Aug 2003

A New Method for the Catalytic Aldol Reaction to Ketones


"A New Method for the Catalytic Aldol Reaction to Ketones"
Kounosuke Oisaki, Yutaka Suto, Motomu Kanai, and Masakatsu Shibasaki

J. Am. Chem. Soc. 2003; 125(19) pp 5644 -5645 DOI Link

Presented by Ryan McFadden.

03 Jul 2003

A General and Efficient Copper Catalyst for the Amidation of Aryl Halides and the N-Arylation of Nitrogen Heterocycles
"A General and Efficient Copper Catalyst for the Amidation of Aryl Halides and the N-Arylation of Nitrogen Heterocycles"
Artis Klapars, Jon C. Antilla, Xiaohua Huang, and Stephen L. Buchwald

J. Am. Chem. Soc. 2001; 123(31) pp 7727 -7729. DOI Link

Presented by Yeeman Ramtohul.

20 Jun 2003

Regioselective Palladium-Catalyzed Arylation of 3-Carboalkoxy Furan and Thiophene


"Regioselective Palladium-Catalyzed Arylation of 3-Carboalkoxy Furan and Thiophene"
Bobby Glover, Kimberly A. Harvey, Bing Liu, Matthew J. Sharp, and Maria F. Tymoschenko

Org. Lett. 2003; 5(3) pp 301 -304. DOI Link

Presented by [unknown].

30 May 2003

Selective C-Arylation of Free (NH)-Heteroarenes via Catalytic C-H Bond Functionalization


"Selective C-Arylation of Free (NH)-Heteroarenes via Catalytic C-H Bond Functionalization"
Bengu Sezen and Dalibor Sames

J. Am. Chem. Soc. 2003; 125(18) pp 5274 -5275. DOI Link

Presented by Dan Caspi.

16 May 2003

C-C Bond Formation via C-H Bond Activation: Catalytic Arylation and Alkenylation of Alkane Segments


"C-C Bond Formation via C-H Bond Activation: Catalytic Arylation and Alkenylation of Alkane Segments"
Bengü Sezen, Roberto Franz, and Dalibor Sames

J. Am. Chem. Soc.; 2002; 124(45) pp 13372 - 13373. DOI Link

Presented by Neil Garg.

02 May 2003

Reversing the Role of the Metal-Oxygen π-Bond. Chemoselective Catalytic Reductions with a Rhenium(V)-Dioxo Complex


"Reversing the Role of the Metal-Oxygen π-Bond. Chemoselective Catalytic Reductions with a Rhenium(V)-Dioxo Complex"
Joshua J. Kennedy-Smith, Kristine A. Nolin, Haluna P. Gunterman, and F. Dean Toste

J. Am. Chem. Soc.; 2003; 125(14) pp 4056 - 4057. DOI Link

Presented by Dave Ebner.

18 Apr 2003

Atom Economy: Aldol-Type Products by Vanadium-Catalyzed Additions of Propargyl Alcohols and Aldehydes
"Atom Economy: Aldol-Type Products by Vanadium-Catalyzed Additions of Propargyl Alcohols and Aldehydes"
Barry M. Trost and Shuichi Oi

J. Am. Chem. Soc.; 2001; 123(6) pp 1230 - 1231. DOI Link

Presented by Raissa Trend.

04 Apr 2003

C-C Bond-Forming Reductive Elimination of Ketones, Esters, and Amides from Isolated Arylpalladium(II) Enolates
"C-C Bond-Forming Reductive Elimination of Ketones, Esters, and Amides from Isolated Arylpalladium(II) Enolates"
Darcy A. Culkin and John F. Hartwig

J. Am. Chem. Soc. 2001; 123(24), 5816 -5817. DOI Link

Presented by Uttam Tambar.

21 Mar 2003

Efficient Nickel-Catalyzed [2 + 2 + 2] Cycloaddition of CO2


"Efficient Nickel-Catalyzed [2 + 2 + 2] Cycloaddition of CO2 and Diynes"
Janis Louie, John E. Gibby, Marc V. Farnworth, and Thomas N. Tekavec

J. Am. Chem. Soc.; 2002; 124(51) pp 15188 - 15189. DOI Link

Presented by Uttam Tambar.

17 Dec 2002